■電極表面pHの数値シミュレーション／Numerical simulation of surface pH

Yoshiharu Mukouyama* and Shuji Nakanishi*

An Ordinary Differential Equation Model for Simulating Local-pH Change at Electrochemical Interfaces

Frontiers in Energy Research, in press, (2020)

https://doi.org/10.3389/fenrg.2020.582284

■光合成の環境応答／Photo-adaptation of natural photosynthesis

Kenya Tanaka, Ginga Shimakawa, Shuji Nakanishi*

Time-of-day-dependent responses of cyanobacterial cellular viability against oxidative stress

Scientific Reports,10, 20029, (2020)

https://www.nature.com/articles/s41598-020-77141-8

■【総説】電解還元によるCO2の資源化／CO2 Electrolysis

Kazuhide Kamiya ,Katsushi Fujii ,Masakazu Sugiyama and Shuji Nakanishi *

CO2 Electrolysis in Integrated Artificial Photosynthesis Systems

Chemistry Letters ()

https://www.journal.csj.jp/doi/abs/10.1246/cl.200691

■リチウムー酸素二次電池／Lithium-oxygen Secondary Batteries

Y. Hase*, K. Nishioka, Y. Komori, T. Kusumoto, J. Seki, K. Kamiya, S. Nakanishi*

Synergistic Effect of Binary Electrolyte on Enhancement of the Energy Density in Li-O2 Batteries

J. Phys. Chem. Lett., 11, 7657–7663 (2020)

https://pubs.acs.org/doi/10.1021/acs.jpclett.0c01877

■リチウムー酸素二次電池／Lithium-oxygen Secondary Batteries

K. Morimoto, T. Kusumoto, K. Nishioka, K. Kamiya, Y. Mukouyama, S. Nakanishi*

Dynamic changes in charge transfer resistances during cycling of aprotic Li–O2 batteries

ACS Appl. Mater. Interfaces, 12, 38, 42803–42810 (2020)

https://pubs.acs.org/doi/10.1021/acsami.0c11382

■配位構造が制御された単一原子触媒の開発 (Award account)／ Single-atom Sites with Designed Coordination Environments

K. Kamiya*

Development of Robust Electrocatalysts Comprising Single-atom Sites with Designed Coordination Environments

Electrochemistry118339–8349 (2020)

https://www.jstage.jst.go.jp/article/electrochemistry/advpub/0/advpub_20-00089/_article/-char/ja

■【総説】生細胞代謝の電気化学制御／Electrochemical Regulation of Cellular Metabolisms

M. Kaneko, K. Ishihara, S. Nakanishi*

Redox‐Active Polymers Connecting Living Microbial Cells to an Extracellular Electrical Circuit

Small (2020)

https://onlinelibrary.wiley.com/doi/10.1002/smll.202001849

■【総説】単一原子触媒による選択電極触媒反応／ Selective single-atom electrocatalysts

K. Kamiya*

Selective single-atom electrocatalysts: a review with a focus on metal-doped covalent triazine frameworks

Chemical Science, 11, 8339-8349, (2020)

https://pubs.rsc.org/en/Content/ArticleLanding/2020/SC/D0SC03328F#!divAbstract

■ガス拡散電極を用いた電気化学的な二酸化炭素の還元反応 ／ Electrochemical CO2 Reduction Using Gas Diffusion Electrode

Y. Wu, K. Kamiya,* T. Hashimoto, R. Sugimoto, T. Harada, K. Fujii, S.Nakanishi*

Electrochemical CO2 Reduction Using Gas Diffusion Electrode Loading Ni-doped Covalent Triazine Frameworks in Acidic Electrolytes

Electrochemistry, in press (2020)

https://www.jstage.jst.go.jp/article/electrochemistry/advpub/0/advpub_20-64036/_article/-char/ja/

■ガス状炭化水素の部分酸化反応／Partial Oxidation of Gaseous Hydrocarbon

S. Kato, K. Iwase, T. Harada, S. Nakanishi,* and K. Kamiya*

"Aqueous Electrochemical Partial Oxidation of Gaseous Ethylbenzene by a Ru-Modified Covalent Triazine Framework"

ACS Appl. Mater. Interfaces,12, 29376–29382 ( 2020)

https://pubs.acs.org/doi/10.1021/acsami.0c07228

【共同研究】3次元カーボン構造体に関する総説

S. Fa, M. Yamamoto, H. Nishihara* , R. Sakamoto* , K. Kamiya* , Y. Nishina* , and T. Ogoshi*

"Carbon-rich materials with three-dimensional ordering at the angstrom level"

Chemical Science,11, 5866-5873 ( 2020)

https://pubs.rsc.org/en/content/articlelanding/2020/sc/d0sc02422h#!divAbstract

【共同研究】光合成微生物太陽電池／Photosynthetic Microbail Fuel Cell

L. Beauzamy, J. Delacotte, B. Bailleul K. Tanaka, S. Nakanishi. F. -A. Wollman, F. Lemaître*

"Mediator-Microorganism Interaction in Microbial Solar Cell: a Fluo-Electrochemical Insight"

Analytical Chemistry, 92, 7532-7539, (2020)

https://doi.org/10.1021/acs.analchem.9b05808

■光電気化学反応の選択性に光強度が及ぼす影響／Photoelectrochemical reaction

K. Kamiya*, R. Sugimoto, T. Tatebe, T. Harada, and S. Nakanishi*

"Light intensity responsive changes of products in photocatalytic reduction of nitrous acid on a Cu‐doped covalent triazine framework/TiO2 hybrid"

ChemSusChem, 13, 3462-3468 (2020)

https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/cssc.202000687

■グリセロール酸化触媒／Electrocatalysts for Glycerol Oxidation

H. Tabata, S. Kato, S. Yamaguchi, T. Harada, K. Iwase, K. Kamiya* and S. Nakanishi*

"Glycerol Oxidation Catalyzed by High-valency Ruthenium Species at Electrochemical Interfaces"

Chemistry Letters, 49, 513-516 (2020)

https://www.journal.csj.jp/doi/abs/10.1246/cl.200056

■M-COF 電極触媒の第一原理計算／ First-principles calculation of M-COF electrode catalyst

K. Iwase, S. Nakanishi, M. Miyayama and K. Kamiya*

"Rational Molecular Design of Electrocatalysts Based on Single-Atom Modified Covalent Organic Frameworks for Efficient Oxygen Reduction Reaction"

ACS Applied Energy Materials, 3, 1644-1652 (2020 )

https://pubs.acs.org/doi/abs/10.1021/acsaem.9b02141

【共同研究】生物時計のレドックス制御／Redoxl Regulation of Biological Rhythms

Masahito Ishikawa, Kazuki Kawai, Masahiro Kaneko, Kenya Tanaka, Shuji Nakanishi, Katsutoshi Hori*

Extracellular electron transfer mediated by a cytocompatible redox polymer to study the crosstalk among the mammalian circadian clock, cellular metabolism, and cellular redox state

RSC Advances,10,1648-1657 (2020)

https://pubs.rsc.org/en/content/articlelanding/2020/ra/c9ra10023g#!divAbstract

【共同研究】細胞代謝の電気化学制御／Electrochemical Regulation of Cellular Metabolisms

M. Kaneko, M. Ishikawa, K. Ishihara*, S. Nakanishi*

"Cell-membrane permeable redox phospholipid polymers induce apoptosis in MDA-MB-231 human breast cancer cells"

Biomacromolecules, 20, 4447-4456 (2019 )

https://pubs.acs.org/doi/10.1021/acs.biomac.9b01184

■光合成の環境応答／Photo-adaptation of natural photosynthesis

K. Tanaka, M. Ishikawa, M. Kaneko, K. Kamiya, S. Kato, S. Nakanishi*

"The endogenous redox rhythm is controlled by a central circadian oscillator in cyanobacterium Synechococcus elongatus PCC7942"

Photosynthesis Research,142, 23 (2019)

https://link.springer.com/article/10.1007%2Fs11120-019-00667-0

【共同研究】リチウム負極電池／Lithium Secondary Batteries

S. Matsuda*, K. Nishioka, S. Nakanishi

"High-throughput combinatorial screening of multi-component electrolyte additives to improve the performance of Li metal secondary batteries"

Scientific Reports,9, 6211 (2019)

https://www.nature.com/articles/s41598-019-42766-x.pdf?origin=ppub

■リチウムー酸素二次電池／Lithium-oxygen Secondary Batteries

K. Nishioka, K. Morimoto, T. Kusumoto, T. Harada, Y. Hase, K. Kamiya, S. Nakanishi*

"Expansion of the potential region for sustained discharge of non-aqueous Li-O2 batteries using an oxygen-enriched carbon cathode"

Chemistry Letters,48,562-565 (2019)

https://www.journal.csj.jp/doi/full/10.1246/cl.190070

■リチウムー酸素二次電池／Lithium-oxygen Secondary Batteries

Y. Hase*, Y. Komori, T. Kusumoto, T. Harada, J. Seki, T. Shiga, K. Kamiya, S. Nakanishi*

"Negative differential resistance as a critical indicator for the discharge capacity of lithium-oxygen batteries"

Nature Communications,10,596 (2019) (Selected as Editor's Highlight)

https://www.nature.com/articles/s41467-019-08536-z

■ヘマタイト電極触媒／Hematite Electrocatalysts

K. Kamiya*, A. Kuwabara, T. Harada, S. Nakanishi*

"Electrochemical formation of Fe(IV)=O derived from H₂O₂ on a hematite electrode as an active catalytic site for selective hydrocarbon oxidation reactions"

ChemPhysChem20, 648-650 (2019) (Front cover)

https://onlinelibrary.wiley.com/doi/10.1002/cphc.201801207

https://onlinelibrary.wiley.com/doi/10.1002/cphc.201900160

■リチウム－固体電解質界面／Lithium-Solid Electrolyte Interface

H. Koshikawa, S. Matsuda, K. Kamiya, M. Miyayama, Y. Kubo, K. Uosaki, K. Hashimoto, S. Nakanishi*,

“Electrochemical impedance analysis of the Li/Au-Li7La3Zr2O12 interface during Li dissolution/deposition cycles: Effect of pre-coating Li7La3Zr2O12 with Au”

J. Electroanl. Chem.,835143 (2019)

https://www.sciencedirect.com/science/article/pii/S157266571930027X

【共同研究】メタン資化菌の電気化学／Electrochemistry of methanotroph

K. Tanaka, S. Yokoe, K. Igarashi, M. Takashiro, M. Ishikawa, K. Hori, S. Nakanishi*, S. Kato*

“Extracellular electron transfer via outer membrane cytochromes in a methanotrophic bacterium Methylococcus capsulatus (Bath) "

Frontier in Microbiology.9, 2905 (2018)

https://www.frontiersin.org/articles/10.3389/fmicb.2018.02905/full

■光誘起電荷移動／Photo-induced charge transfer

T. Tatebe, T. Harada, K. Kamiya*, S. Nakanishi*

“Photo-induced direct interfacial charge transfer at TiO2 modified with hexacyanoferrate(III)"

Photochem. Photobio. Sci.17,1153 (2018)

http://pubs.rsc.org/en/content/articlelanding/2018/pp/c8pp00237a#!divAbstract

■CO2還元電極触媒／Electrochemical CO2 reduction catalysts

P. Su[†], K. Iwase[†], T. Harada, K. Kamiya*, S. Nakanishi*

([†] Both authors equally contributed to this work.) “Covalent triazine framework modified with coordinatively-unsaturated Co or Ni atoms for CO2 electrochemical reduction”

Chem. Sci.9,3941 (2018) (OPEN ACCESS, Highlighted in ChemSciPick and Chemistry world)

http://pubs.rsc.org/en/content/articlelanding/2018/sc/c8sc00604k#!divCitation

■カスケード型電子移動触媒／Cascade-type Electron Transfer Catalysts

K. Kamiya, T. Tatebe, S. Yamamura, K. Iwase, T. Harada, S. Nakanishi*

“Selective reduction of nitrate by the local cell catalyst composed of metal-doped covalent triazine frameworks”

ACS catal.8,2693 (2018)

https://pubs.acs.org/doi/10.1021/acscatal.7b04465

■酸素還元触媒／Oxygen Reduction Electrocatalysts

K. Iwase, K. Kamiya*, M. Miyayama, K. Hashimoto and S. Nakanishi*

"Sulfur-Linked Covalent Triazine Frameworks doped with Coordinatively-Unsaturated Cu(I) as Electrocatalysts for Oxygen Reduction"

ChemElectroChem5,805 (2018)

http://dx.doi.org/10.1002/celc.201701361　

■ニトロベンゼン選択還元触媒／Selective Electrocatalysts for Nitrobenzene Reduction

K. Iwase, N Fujinami, K. Hashimoto, K. Kamiya*, and S. Nakanishi*

"Cooperative Electrocatalytic Reduction of Nitrobenzene to Aniline in Aqueous Solution by Copper Modified Covalent Triazine Framework"

Chem. lett.47304 (2018)

http://www.journal.csj.jp/doi/abs/10.1246/cl.171117

■リチウム－固体電解質界面／Lithium-Solid Electrolyte Interface

H. Koshikawa, S. Matsuda, K. Kamiya, M. Miyayama, Y. Kubo, K. Uosaki, K. Hashimoto, S. Nakanishi*,

“Dynamic changes in charge-transfer resistance at Li metal/Li7La3Zr2O12 interfaces during electrochemical Li dissolution/deposition cycles”

J. Power Sources376,147 (2018)

https://www.sciencedirect.com/science/article/pii/S0378775317315653

■アルコール選択酸化電極触媒／Selective Electrocatalysts for Alcohol Oxidation

S. Yamaguchi, K. Kamiya*, K. Hashimoto, S. Nakanishi*,

“Ru atom-modified covalent triazine framework as a robust electrocatalyst for selective alcohol oxidation in aqueous electrolytes”

Chem. Commun.53,10437-10440 (2017)

http://pubs.rsc.org/en/content/articlelanding/2014/cc/c7cc05841a

■ペロブスカイト太陽電池／Perovskite Solar Cells

H. K. Adli,T. Harada, S. Nakanishi, S. Ikeda

Effects of TiCl4 Treatment on Structural and Electrochemical Properties of a Porous TiO2 Layer in CH3NH3PbI3 Perovskite Solar Cells

PhysChemChemPhys, 19,26898-26905 (2017)

http://pubs.rsc.org/en/content/articlelanding/2014/cc/c7cc05841a

【共同研究】

H. Nishihara*, T. Hirota, K. Matsuura, M. Ohwada, N. Hoshino, T. Akutagawa, T. Higuchi, H. Jinnai, Y. Koseki, H. Kasai, Y. Matsuo, J. Maruyama, Y. Hayasaka, H. Konaka, Y. Yamada, S. Yamaguchi, K. Kamiya, T. Kamimura, H. Nobukuni, F. Tani*,

Synthesis of ordered carbonaceous frameworks from organic crystals

Nature Commun. 8,109 (2017)

https://www.nature.com/articles/s41467-017-00152-z

■メタン資化菌の電気化学／Electrochemistry of methanotroph

M. Ishikawa, Y. Tanaka, R. Suzuki, K. Kimura, K. Tanaka, K. Kamiya, H. Ito, S. Kato, K. Kamachi, K. Hori, S. Nakanishi*

Real-time monitoring of intracellular redox changes in Methylococcus capsulatus (Bath) for efficient bioconversion of methane to methanol

Bioresource Technology ,241,1157-1161 (2017)

http://www.sciencedirect.com/science/article/pii/S0960852417307629

■リチウム酸素電池の高容量化／Lithium-O2 batteries with high capacity

S.Matsuda, K. Uosaki, S. Nakanishi*

Enhanced energy capacity of lithium-oxygen batteries with ionic liquid electrolytes by addition of ammonium ions

J. Power Sources.,356,12-17 (2017)

http://www.sciencedirect.com/science/article/pii/S0378775317305645

■リチウム負極反応の制御／Control of Lithium Negative Electrode

S.Matsuda, Y. Kubo, K. Uosaki, S. Nakanishi*

Lithium-metal deposition/dissolution within internal space of CNT 3D matrix results in prolonged cycle of lithium-metal negative electrode

Carbon,119,119-123 (2017)

http://www.sciencedirect.com/science/article/pii/S0008622317303937

S.Matsuda, K. Uosaki, S. Nakanishi*

Improved charging performance of Li-O2 batteries by forming Ba-incorporated Li2O2 as the discharge product

J. Power Sources.,353,138-143 (2017)

http://www.sciencedirect.com/science/article/pii/S0378775317304895

S.Matsuda, Y. Kubo, K. Uosaki, S. Nakanishi*

Insulative Microbiber 3D-Matrix as a Host Material Minimizing Volume Change of the Anode of Li-Metal Batteries

ACS Energy Letters,2,924-929 (2017)

http://pubs.acs.org/doi/abs/10.1021/acsenergylett.7b00149

H. Koshikawa, S. Matsuda, K. Kamiya, Y. Kubo, K. Uosaki, K. Hashimoto, S. Nakanishi*

Effects of contaminant water on coulombic efficiency of lithium deposition/dissolution reactions in tetraglyme-based electrolytes

J. Power Sources,350,73-79 (2017)

http://www.sciencedirect.com/science/article/pii/S0378775317303257

S. Matsuda, Y. Kubo, K. Uosaki, S. Nakanishi*

Potassium Ions Promote Solution-Route Li2O2 Formation in the Positive Electrode Reaction of Li-O2 Batteries

J. Phys. Chem. C,8,1142-1146 (2017)

http://pubs.acs.org/doi/abs/10.1021/acs.jpclett.7b00049

K. Tanaka, M. Kaneko, M. Ishikawa, S. Kato, T. Kamachi, H. Ito, K. Kamiya, S. Nakanishi*

Specific interaction between redox phospholipid polymers and plastoquinone in photosynthetic electron transport chain

ChemPhysChem,18,878-881 (2017)

http://onlinelibrary.wiley.com/doi/10.1002/cphc.201700065/full

R. Kamai, S. Nakanishi, K. Hashimoto*, K. Kamiya*

Selective electrochemical reduction of nitrogen oxides by covalent triazine frameworks modified with single Pt atoms

J. Electroanal. Chem.800,54-59 (2017)

http://www.sciencedirect.com/science/article/pii/S1572665716304854

M. Kaneko, M. Ishikawa, J. Song, S. Kato, K. Hashimoto*, S. Nakanishi*

Cathodic supply of electrons to living microbial cells via cytocompatible redox-active polymers

Electrochemistry Communications, 75,17-20 (2017)

http://www.sciencedirect.com/science/article/pii/S1388248116302934

M. Kaneko, M. Ishikawa, K. Hashimoto*, S. Nakanishi*

Molecular Design of Cytocompatible Amphiphilic Redox-active Polymers for Efficient Extracellular Electron Transfer

Bioelectrochemistry,114,8-12 (2016)

http://www.sciencedirect.com/science/article/pii/S1567539416301827

H. Koshikawa, S. Nakanishi, K. Hashimoto*, K. Kamiya*

Catalytic methane combustion over iron/nitrogen-doped silicon carbide

RSC Advances,6,85559-85563 (2016)

http://pubs.rsc.org/en/content/articlelanding/2016/ra/c6ra16318a

R. Kamai, K. Kamiya, K. Hashimoto*, S. Nakanishi*

Oxygen-tolerant electrodes with Pt-loaded covalent triazine frameworks for the hydrogen oxidation reaction

(Selected as HOT paper)Angew. Chem. Int. Ed.55,13184–13188 (2016) (R.K and K.K equally contributed to this work)

http://onlinelibrary.wiley.com/doi/10.1002/anie.201607741/abstract

P. Su, K. Iwase, S. Nakanishi, K. Hashimoto*, K. Kamiya*

Nickel-Nitrogen-Modified Graphene: An Efficient Electrocatalyst for the Reduction of Carbon Dioxide to Carbon Monoxide

Small,12,6083-6089 (2016)

http://onlinelibrary.wiley.com/wol1/doi/10.1002/smll.201602158/abstract

S. Matsuda, Y. Kubo, K. Uosaki, K. Hashimoto*, and S. Nakanishi*

Improved Energy Capacity of Aprotic Li-O2 Batteries by Forming Cl-Incorporated Li2O2 as the Discharge Product

J. Phys. Chem. C,120,13360-13365 (2016)

http://pubs.acs.org/doi/abs/10.1021/acs.jpcc.6b03083

T. Yoshioka, K. Iwase, S. Nakanishi, K. Hashimoto*, and K. Kamiya*

Electrocatalytic Reduction of Nitrate to Nitrous Oxide by a Copper-Modified Covalent Triazine Framework

J. Phys. Chem. C, 120,15729-15734 (2016)

http://pubs.acs.org/doi/abs/10.1021/acs.jpcc.5b10962

Y. Zhao, K. Kamiya, K. Hashimoto*. S. Nakanishi*

Efficient Oxygen Reduction Reaction Electrocatalysts Synthesized from Iron-coordinated Aromatic Polymer Precursors

J. Mater. Chem. A,4,3858-3865 (2016)

http://pubs.rsc.org/en/content/articlelanding/2016/ta/c5ta08316h#!divAbstract

S. Song, D. Sasaki, K. Sasaki, S. Kato, A. Kondo, K. Hashimoto*, S. Nakanishi*

Comprehensive metabolomic analyses of anode-respiring Geobacter sulfurreducens cells: The impact of anode-respiration activity on intracellular metabolite levels

Process Biochemistry, 51,34-38 (2016)

http://www.sciencedirect.com/science/article/pii/S1359511315301215